Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment          下载免费PDF全文

Zanist Q. Hama‐Aziz  Kevin M. Hiscock  Richard J. Cooper 《水文研究》2017,31(6):1371-1381

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.  相似文献   

Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed     

Lucy A. Rose  Diana L. Karwan 《水文研究》2021,35(12):e14455

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献   

Chloride source delineation in an urban-agricultural watershed: Deicing agents versus agricultural contributions     

Andrew Oberhelman  Eric W. Peterson 《水文研究》2020,34(20):4017-4029

Analyses (n = 525) of chloride (Cl⁻), bromide (Br⁻), nitrate as nitrogen (NO₃-N), sodium (Na⁺), calcium (Ca²⁺) and potassium (K⁺) in stream water, tile-drain water and groundwater were conducted in an urban-agricultural watershed (10% urban/impervious, 87% agriculture) to explore potential differences in the signature of Cl⁻ originating from an urban source as compared with an agricultural source. Only during winter recharge events did measured Cl⁻ concentrations exceed the 230 mg/L chronic threshold. At base flow, nearly all surface water and tile water samples had Cl⁻ concentrations above the calculated background threshold of 18 mg/L. Mann–Whitney U tests revealed ratios of Cl⁻ to Br⁻ (p = .045), to NO₃-N (p < .0001), to Ca²⁺ (p < .0001), and to Na⁺ (p < .0001) to be significantly different between urban and agricultural waters. While Cl⁻ ratios indicate that road salt was the dominant source of Cl⁻ in the watershed, potassium chloride fertilizer contributed as an important secondary source. Deicing in watersheds where urban land use is minimal had a profound impact on Cl⁻ dynamics; however, agricultural practices contributed Cl⁻ year-round, elevating stream base flow Cl⁻ concentrations above the background level.  相似文献   

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream     

Sam J. Leuthold  Stephanie A. Ewing  Robert A. Payn  Florence R. Miller  Stephan G. Custer 《水文研究》2021,35(2):e14029

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   

川东北宣汉地区新型杂卤石钾盐矿的地球化学特征及其意义   总被引：2，自引：2，他引：0  

商雯君  张永生  李空  邢恩袁  桂宝玲  彭渊  赵海彤 《矿床地质》2020,39(2):369-380

新型杂卤石钾盐矿分布于川东北宣汉地区早-中三叠世蒸发岩层中,以杂卤石碎屑不均匀的分布于石盐层为特征。笔者对HC3井新型杂卤石钾盐矿段进行连续取样,并进行水溶化学实验,根据其可溶部分的主量、微量元素特征发现:①溶液中的(K+Mg)/Ca值平均为1.24,略小于杂卤石中的(K+Mg)/Ca值(1.27),整体损失率为2.36%,远小于CaSO4组分在杂卤石中的含量(48%),表明杂卤石在石盐基质溶解形成的NaCl溶液中有较好的溶解度,有利于溶采;②Br×103/Cl值分布在0.16～0.44,显示新型杂卤石钾盐矿的蒸发阶段位于正常石盐阶段内,整体较高,蒸发阶段稳定无剧烈波动,仅顶部出现快速淡化,结合前人对杂卤石的成因研究,笔者认为石盐层不具备形成杂卤石的条件,杂卤石碎屑是一种"外来物";③含硬石膏碎屑中,(K+Mg)/Ca值随着Br×103/Cl值的增加而增高,表明碎屑中的杂卤石的含量随成盐卤水浓缩程度的升高而增加。  相似文献   

凤太矿集区东塘子铅锌矿床S、Pb同位素组成对成矿物质来源的示踪     

张革利  田涛  王瑞廷  高卫宏  常宗东 《中国地质》2020,47(2):472-484

东塘子铅锌矿床是秦岭成矿带中典型的铅锌矿床之一,前人对东塘子铅锌矿床成矿作用研究较多,但受限于测试手段及认识的局限性,多年来对其物质来源的认识仍未统一。本文在充分研究东塘子铅锌矿床地质特征的基础上,开展了相关样品的S、Pb同位素分析,分析对象包括了不同类型的铅锌矿石,讨论了该铅锌矿床的成矿物质来源、区内岩浆岩与铅锌成矿的关系等。研究表明:东塘子铅锌矿床矿石硫化物δ34S值变化范围为1.8‰～12.5‰,平均7.50‰,计算获得成矿流体中总硫δ34S∑S为7.7‰,显示海水硫酸盐(蒸发膏岩)与岩浆硫的混合来源特征。矿石铅同位素组成稳定,铅源主要来自富U-Th-Pb的上地壳与深部,可能与深部岩浆活动有关。研究结果表明,东塘子铅锌矿床的成矿过程与南秦岭印支期大规模多阶段构造-岩浆-流体活动密切相关,为下一阶段区内找矿工作提供了新的思路。  相似文献   

大连长兴岛海域疏浚区GF-1 WFV影像悬浮物遥感反演研究     

王林  陈艳拢  袁仲杰  赵建华  孟庆辉  赵素芳  王祥  王新新 《海洋技术学报》2019,38(1)

利用2017年8-9月期间大连长兴岛海域实测遥感反射率、悬浮物浓度及GF-1 WFV数据,研究了该区域悬浮物浓度的遥感反演算法,发现遥感反射率与悬浮物浓度的散点图存在两种不同的变化趋势,将2008-2015年期间辽东湾内其它海域的数据与长兴岛海域数据进行叠加后,可初步推断产生两种变化趋势的主要原因在于疏浚区与非疏浚区悬浮物的粒径大小不同,导致其光学特性和反演算法也存在差异。将两种算法分别应用于2017年9月20日辽东湾及长兴岛近岸海域的GF-1 WFV4影像,发现采用非疏浚区算法反演长兴岛海域悬浮物浓度时,出现明显的低估现象,而疏浚区算法则能较好地反映出疏浚施工过程中悬浮物的分布规律,具有较好的工程应用价值。  相似文献   

Soil cracking effects on hydrological and erosive processes: a study case in Mediterranean cultivated vertisols          下载免费PDF全文

Nesrine Inoubli  Damien Raclot  Roger Moussa  Hamadi Habaieb  Yves Le Bissonnais 《水文研究》2016,30(22):4154-4167

Shrink–swell soils, such as those in a Mediterranean climate regime, can cause changes in terms of hydrological and erosive responses because of the changing soil water storage conditions. Only a limited number of long‐term studies have focused on the impacts on both hydrological and erosive responses and their interactions in an agricultural environment. In this context, this study aims to document the dynamics of cracks, runoff and soil erosion within a small Mediterranean cultivated catchment and to quantify the influence of crack processes on the water and sediment supplied to a reservoir located at the catchment outlet using water and sediment measurements at a cultivated field outlet as baseline. Detailed monitoring of the presence of topsoil cracks was conducted within the Kamech catchment (ORE OMERE, Tunisia), and runoff and suspended sediment loads were continuously measured over a long period of time (2005–2012) at the outlets of a field (1.32 ha) and a catchment (263 ha). Analysis of the data showed that topsoil cracks were open approximately half of the year and that the rainfall regime and water table level conditions locally control the seasonal cracking dynamics. Topsoil cracks appeared to seriously affect the generation of runoff and sediment concentrations and, consequently, sediment yields, with similar dynamics observed at the field and catchment outlets. A similar time lag in the seasonality between water and sediment delivery was observed at these two scales: although the runoff rates were globally low during the presence of topsoil cracks, most sediment transport occurred during this period associated with very high sediment concentrations. This study underlines the importance of a good prediction of runoff during the presence of cracks for reservoir siltation considerations. In this context, the prediction of cracking effects on runoff and soil erosion is a key factor for the development of effective soil and water management strategies and downstream reservoir preservation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

纳米铁还原脱氮动力学及其影响因素   总被引：3，自引：1，他引：2  

黄园英  秦臻  刘丹丹  王晓春 《岩矿测试》2011,30(1):53-58

饮用水中硝酸盐(NO3-)对人体健康有危害。为了去除水溶液中NO3-,在实验室制得纳米铁颗粒。它的粒径为20～40 nm,比表面积(BET)为49.16 m2/g。本研究通过批实验考察了纳米铁对NO3-还原脱氮动力学性质和影响NO3-脱氮快慢的主要因素,如反应pH、纳米铁投加量和NO3-起始浓度。实验结果表明,pH越低越有利于NO 3-还原。在一定范围内,NO 3-还原速率随纳米铁投加量增加而增大,而随NO 3-起始浓度升高而降低,反应遵循准一级反应动力学方程,表面吸附和氧化还原反应是纳米铁对NO3-脱氮的主要去除机理。纳米铁对NO3-还原过程中可能反应的途径进行了讨论,NO3-还原产物取决于反应条件。在本研究条件下,纳米铁对NO3-脱氮的最终产物主要为NH4+-N而不是N2,必须进行更多的研究来解决这一问题。  相似文献   

电感耦合等离子体发射光谱法和火焰原子吸收光谱法连续测定化探样品中12个元素   总被引：3，自引：3，他引：0  

于阗  张连起  陈小迪 《岩矿测试》2011,30(1):71-74

建立了地质化探样品中不同含量和检出限要求的12个元素的连续测定方法。样品经一次取样,用盐酸-氢氟酸-硝酸-高氯酸溶样,电感耦合等离子体发射光谱法测定铜、铅、锌、钴、镍、镉、锶、钡、钒、锰后,加碘化钾-甲基异丁基甲酮萃取分离,火焰原子吸收光谱法测定银、镉。银、镉的相对标准偏差(RSD,n=12)分别为6.5%、4.7%。与现行分析方法相比,建立的方法灵敏度和精密度高、准确度好,降低了生产成本,缩短了检测时间,尤其适合大量化探样品的测定。  相似文献